非晶态YBO结构与甲苯催化燃烧性能研究
首发时间:2025-05-16
摘要:甲苯作为一种典型的挥发性有机污染物(VOCs),在空气中的扩散可引发心血管疾病等健康问题,通过催化燃烧技术高效降解甲苯已引起研究人员的广泛关注。通过溶胶凝胶法调控成相温度制备系列非晶态YBO催化剂,结合XRD、TEM及FT-IR技术表征材料非晶特性,并用于高效甲苯催化燃烧反应。结果表明,YBO-1构型中的表面氧缺陷和三配位的B中心作活性位点,在350 ℃即可完全催化甲苯转化为CO2和H2O;进一步负载贵金属Pd,反应T90低至226 ℃。研究揭示了非晶态YBO材料的基本结构单元与催化机制,为开发新型VOCs催化燃烧材料提供了理论依据和实践参考。
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Research on the Amorphous YBO Structure and Its Catalytic Combustion Performance for Toluene
Abstract:Toluene, as a typical volatile organic compound (VOCs), poses health risks such as cardiovascular diseases through atmospheric diffusion. The efficient degradation of toluene via catalytic combustion technology has attracted significant research attention. A series of amorphous YBO catalysts were synthesized by adjusting phase formation temperature through the sol-gel method. The amorphous characteristics were characterized using XRD, TEM, and FT-IR techniques, and their performance in catalytic toluene combustion was evaluated. Results demonstrate that the surface oxygen defects and three-coordinated boron centers in YBO-1 configuration serve as active sites, achieving complete conversion of toluene to CO2 and H2O at 350 C. Further loading with noble metal Pd reduced the T90 temperature to 226 C. This study elucidates the fundamental structural units and catalytic mechanisms of amorphous YBO materials, providing both theoretical foundations and practical references for developing novel catalytic combustion materials for VOCs treatment.
Keywords: VOCs Amorphous materials Toluene Catalytic combustion YBO
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