分级多孔碳的设计及在锂硫电池的研究
首发时间:2025-05-09
摘要:分级多孔碳材料,以其独特的微孔、介孔和大孔结构,展现出在储能和催化等领域的巨大潜力。尤其是作为正极材料,分级多孔碳材料能有效解决锂硫电池的穿梭效应,提高电池的循环稳定性和容量保持率。本文综述了分级多孔碳材料的设计及其在锂硫电池中的应用,详细阐述了硬模板法、软模板法和自模板法等制备分级多孔碳材料的常用方法,并通过具体实例展示了这些方法在提升锂硫电池性能方面的应用效果。展望了分级多孔碳材料未来的研究方向,包括开发低成本、可规模化的制备方法,以及深入研究多级孔道内硫的反应状态等,为实现高能量密度锂硫电池的商业化提供重要路径。
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Design of graded porous carbon and study in lithium-sulfur batteries
Abstract:Graded porous carbon materials, with their unique microporous, mesoporous and macroporous structures, show great potential in fields such as energy storage and catalysis.Especially as anode materials, graded porous carbon materials can effectively solve the shuttle effect of lithium-sulfur batteries and improve the cycle stability and capacity retention of the batteries.This paper reviews the design of graded porous carbon materials and their applications in lithium-sulfur batteries, elaborates on the common methods of preparing graded porous carbon materials such as hard template method, soft template method and self-template method, and demonstrates the application effects of these methods in enhancing the performance of lithium-sulfur batteries through specific examples.The future research directions of graded porous carbon materials are envisioned, including the development of low-cost and scalable preparation methods, and the in-depth study of the reaction state of sulfur within the multistage pores, etc., which will provide an important pathway for the commercialization of high-energy-density lithium-sulfur batteries.
Keywords: Porous carbon Template method Graded porous carbon Lithium-sulfur batteries
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