电极表面润湿性调节应用于电解水的研究进展
首发时间:2021-12-24
摘要:电解水作为一种绿色无污染的能源转换技术,能够以水为原料高效产出氢能,因而引起了研究者们的广泛关注。但是电解水的两个半反应--氧析出反应(OER)和氢析出反应(HER)的反应动力学极为缓慢,因此需要高效的催化剂来加速反应。除了对催化剂种类的广泛研究之外,具有特殊润湿能力的电极表面可以为解决析气反应中气体扩散难题提供新的设计思路,越来越多的人们开始关注在催化反应过程中的气体传输/扩散行为的调节,以形成具有高反应速率和优异长期稳定性的催化系统。本文将简要介绍电极在空气/水下润湿状态的基本原理,讨论电解水过程中两个析气反应的润湿性相关设计原则的近况,并概述了现存问题和对未来进行展望。
关键词: 应用化学 电解水 氧析出反应 氢析出反应 电极表面 润湿性调节
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Research progress of electrode surface wettability adjustment applied to electrolytic water
Abstract:As a green and pollution-free energy conversion technology, water splitting can produce hydrogen energy efficiently with water as raw material, which has attracted extensive attention of researchers. However, the reaction kinetics of the two half reactions of water splitting, oxygen evolution reaction (OER) and hydrogen evolution reaction (HER), is extremely slow, so efficient catalysts are needed to accelerate the reaction. In addition to extensive research on the types of catalysts, the electrode surface with special wettability can provide new design ideas for solving the problem of gas diffusion in gas evolution reaction. More and more people begin to pay attention to the regulation of gas transmission/diffusion behavior in the process of electrocatalytic reaction. To form a catalytic system with high reaction rate and excellent long-term stability. This review will briefly introduce the basic principle of electrode wetting state in air/water, discuss the current progress of wettability related design principles of two gas evolution reactions in the process of electrolytic water, summarize the existing problems and prospects for the future.
Keywords: apllied chemistry water splitting oxygen evolution reaction hydrogen evolution reaction electrode surface wettability regulation
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电极表面润湿性调节应用于电解水的研究进展
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