热处理对不同颜色番茄中类胡萝卜素的降解和异构化的影响
首发时间:2020-03-12
摘要:不同颜色番茄中类胡萝卜素的组成不同,其在热加工中的变化也存在较大差异。采用YMC Carotenoid C30-HPLC系统分析了市面上常见的两种橙色番茄和一种红番茄的类胡萝卜素组成,并对比了热处理对三种番茄中类胡萝卜素的降解和异构化的影响。结果表明,橙色番茄-1中顺式番茄红素质量分数达99.24%,远远高于红番茄的8.48%。而橙色番茄-2,具有与橙色番茄-1相似的颜色,但是主要类胡萝卜素为β-胡萝卜素,且顺式异构体仅占6.74%。从热处理结果来看,对于红番茄和橙色番茄-2,番茄红素和β-胡萝卜素总量影响较小,仅有少量损失,且仅伴随着少部分的全反式-顺式的异构化转变,而不同的是,对于橙色番茄-1,番茄红素总量损失比较明显,且7,9,7\',9\'-四顺式番茄红素会逐渐异构化为全反式、5-顺和其他顺式番茄红素,同时,两种重要的无色类胡萝卜素--六氢番茄红素和八氢番茄红素总量都比较稳定,且八氢番茄红素未观察到构型变化。以上信息对综合利用不同颜色的番茄原料和研发高生理活性的番茄产品具有重要意义。
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Effects of Thermal Processing on the Degradation and Isomerization of Carotenoids in Coloured-tomatoes
Abstract:Carotenoid composition in colored tomatoes are different and so are their changes, eg. isomerization and degradation, during thermal processing.The carotenoids of two orange tomato varieties and one red tomato variety were analysed using YMC Carotenoid C30-HPLC system. Additionally, effects of the thermal processing on degradation and isomerization of carotenoids in these tomatoes were evaluated. The results showed that the mass fraction of cis-lycopene of orange tomato-1 reached 99.24%, which was much higher than 8.48% of red tomato. For orange tomato-2, it showed the similar colour to orange tomato-1, β-carotene was its main carotenoid compound, and the cis-isomers only accounted for 6.74%. The results of heat treatment showed that , for red tomato and orange tomato-2, the degradation and isomerization were not obvious in whether lycopene or β-carotene. Differently, for orange tomato-1, the loss of total lycopene was obvious, and tetra-cis-lycopene was gradually isomerized to all-trans-, 5-cis, and other-cis-lycopene. Meanwhile, the colourless carotenoids (phytofluene and phytoene) remained stable and the isomerization was not observed in phytoene. These information was useful to make use of the great material and research and develop tomato products with high bioactivty.
Keywords: food science tomato carotenoids isomers degradation isomerization
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热处理对不同颜色番茄中类胡萝卜素的降解和异构化的影响
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