Facile approach to synthesize uniform Au@mesoporousSnO2 yolk-shell nanoparticles and their excellent catalytic activity in 4-nitrophenol reduction

• 1、School of Chemistry & Environmental Engineering, Changchun University of Science & Technology, Changchun, 130022
• 2、College of Chemistry, Northeast Normal University, Changchun, 130024

Abstract：Uniform and monodispersed Au@mSnO2 yolk-shell NPs composed the moveable Au NP cores and mSnO2 shells have been successfully fabricated via a facile approach. The outside mSnO2 shells of Au@mSnO2 yolk-shell NPs not only prevent Au NPs from aggregating and corroding by the reaction solution, but also allow the Au NPs to contact with reactant molecules easily through the mesoporous channels. The synthesized materials exhibit excellent catalytic performance and stability towards the reduction of 4-nitrophenol with NaBH4 as a reducing agent, which may be ascribed to their high specific surface area and unique mesoporous structure. Moreover, the synthetic strategy reported in this paper can be extended to fabricate a series of multifunctional noble metal@metal oxide yolk-shell nanocomposite materials with unique properties for various applications.

Keywords： yolk-shell nanoparticles；mesoporous；p-nitrophenol