高分子固体电解质与AL阳极键合性能研究
首发时间:2015-05-04
摘要:为了提高MEMS的封装技术,采用高分子固体电解质(PEO-LiClO4)与AL阳极键合的方法进行封装。通过对实验工艺参数的分析,键合电压和预热温度影响锂离子的迁移数和导电性,而导电性的好坏是能否键合的关键,红外光谱(FTIR)说明了高分子固体电解质的导电机理,即Li+先与ClO4-离解然后与C-O 产生络合。 X射线衍射(XRD)分析相对于LiPF6和LiBF4而言LiClO4与PEO发生的反应消弱了络合结构,使得络合结构松散,在强静电场的作用下促进了锂离子的扩散和迁移。通过扫描电子显微镜( SEM)、超景深显微观察、能谱仪( EDS)对键合后界面的分析,说明过渡层的产生是得以焊合的关键。
For information in English, please click here
Solid electrolyte and anodic properties of the polymer AL
Abstract:In order to improve the packaging of MEMS technology, the use of solid polymer electrolyte (PEO-LiClO4) and AL anodic bonding method closure. Through analysis of the experimental process parameters, voltage and preheating temperature bonding influence transport number of lithium ions and conductivity, and electrical conductivity is good or bad is the key to the bonding, infrared spectroscopy (FTIR) described polymer solid electrolyte the conductive mechanism, namely Li + first and then with CO dissociation ClO4- produce complex. X-ray diffraction (XRD) analysis with respect to the response in terms of LiClO4 and LiPF6 and LiBF4 PEO occurred weakened complex structure, making complex structure is loose, in the role of a strong electrostatic field to promote the proliferation and migration of lithium ions. By scanning electron microscopy (SEM) observations, ultra deep microscopic observation, dispersive spectroscopy (EDS) of the bonded interface analysis shows that the transition layer is the key to produce the weld.
Keywords: solid polymer electrolyte (SPE) anodic bonding the transition layer
论文图表:
引用
No.4640819105385514****
同行评议
共计0人参与
勘误表
高分子固体电解质与AL阳极键合性能研究
评论
全部评论