南京市化工行业非甲烷挥发性有机物排放清单研究
首发时间:2015-04-27
摘要:基于详细的企业调查信息建立了南京市化工行业非甲烷挥发性有机物(Non-methane volatile organic compounds, NMVOC)排放清单。2011年南京市化工行业NMVOC排放量约为11.2万吨,其中石油炼制贡献了化工行业总量的51.5%,基础化工原料、合成化工、精细化工、炼焦、其它化工贡献依次为13.3%、12.0%、11.4%、8.0%、3.8%。排放被分解为139种组分,其中烯烃对臭氧生成潜势(Ozone formation potential, OFP)的贡献超过58%。基于公开发表的统计资料对同一城市和年份的化工行业NMVOC排放进行重新计算,并将两种方法的结果进行对比,发现基于统计资料的方法因遗漏了基础化学原料、合成化工中的部分排放源而导致对化工行业NMVOC排放约18.8%的低估。根据人口分布NMVOC排放进行空间分配,得到的结果未能较好反映重点排放源地理位置的影响。上述对比证实在城市尺度进行详细排放源调查对改善排放清单具有重要作用。?????
关键词: 挥发性有机物 排放清单 化工行业 企业调查信息 南京市?????
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Study on emission inventory of non-methane volatile organic compounds for chemical industry in Nanjing
Abstract:An emission inventory of non-methane volatile organic compounds (NMVOC) for chemical industry in Nanjing was developed, based on detailed enterprise information from plant-by-plant onsite survey. The NMVOC emissions were estimated at 112 Giga grams (Gg) for chemical industry in Nanjing, 2011. Oil refinery, basic chemical material manufacturing, synthetic chemical industry, fine chemical industry, coke making and other chemical industry contributed 51.5%, 13.3%, 12.0%, 11.4%, 8.0%, and 3.8%, respectively. The total NMVOC emissions were speciated into 139 individual species, in which the alkenes contributed more than 58% to the total ozone formation potential (OFP). Besides, the NMVOC emissions from chemical industry for the same city and year were also calculated based on statistical data, and were then compared with results from the plant-based method. It was found that the NMVOC emissions based on statistical data were underestimated by 18.8% because of the omission of some emission sources in basic chemical material manufacturing and synthetic chemical industry. Besides, the spatial allocation of emissions according to population density failed to capture the emissions from the key emission sources. The comparisons between the two inventories demonstrated the importance of conducting detailed survey on improvement of emission inventory at city scale.
Keywords: volatile organic compounds emission inventory chemical industry enterprise information from onsite survey Nanjing?
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